What it is and when to use it
This calculator covers the two most common ways an analyst prepares a standard solution for titration: weighing out a solid reagent directly, or diluting a concentrated stock solution to a working concentration. Enter the target molarity and final volume once, and the tool returns the solute mass to weigh on the balance, the stock volume to pipette if you are diluting instead, and the diluent volume needed to bring either path to the final volume.
Use the solute mass result when you are making a primary or working standard from a solid reagent (such as NaCl, KHP, or sodium carbonate) and need to know exactly how many grams to weigh. Use the stock volume and diluent volume results when a concentrated stock solution already exists and you only need to dilute it down. The purity and hydrate factor fields correct the weighed mass for reagents that are not 100% pure or that carry water of crystallization (for example, borax as Na2B4O7·10H2O).
Mass (g) = (M × V × MW × hydrate factor) / (purity / 100)
Worked example
Preparing 1 L of a 0.1 M standard from solid sodium chloride (molar mass 58.44 g/mol) that is 99% pure, with no hydrate: Mass = (0.1 × 1 × 58.44 × 1) / (99/100) = 5.844 / 0.99 = 5.903 g, matching the calculator's default output. For the dilution path with a 1 M stock and no density correction: Stock volume = (0.1 × 1) / 1 = 0.1 L = 100 ml, and diluent volume = 1000 − 100 = 900 ml of solvent to bring the flask to the 1 L mark.
Common mistakes and how to interpret the result
- Forgetting the hydrate factor. Weighing a hydrated salt as if it were anhydrous under-delivers the actual moles of solute, since part of the weighed mass is water. Set the hydrate factor to the ratio of the hydrate's molar mass to the anhydrous molar mass.
- Using the label purity from an old bottle. Purity can drift as reagents absorb moisture; check the current Certificate of Analysis when precision matters, especially for primary standards.
- Mixing the two workflows. The solute mass result assumes you are weighing solid reagent; the stock volume and diluent volume results assume you already have a liquid stock. Use only the pair of numbers that matches your actual prep method.
- Ignoring glassware calibration temperature. Volumetric flasks are calibrated at a reference temperature (usually 20°C); preparing or reading volume far from that temperature introduces a small but real error the temperature field only partially accounts for.